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That's porphyrin, a mucus secreted from their eyes and/or nose. Lots of it can indicate respiratory illness. Have a listen to his breathing/lungs (hold his chest up next to your ear) they should be completely silent with no wheezing or any other noises. It may be he's just woken up and hasn't had time to clean it off, though. Have a listen to his breathing and sit tight to see if it stays there.
 
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